State-to-State Chemistry

Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 State-to-State Cross Sections and Rate Constants for Reactions of Neutral Molecules......Page 9
Early \"bulk\" experiments involving vibrationally excited reagents.......Page 13
Quantitative experiments involving vibrationally excited diatomics.......Page 14
Theoretical considerations regarding vibrational enhancement effect.......Page 17
Influence of reagent\'s rotational energy upon reactivity......Page 21
Literature Cited......Page 24
2 State-to-State Ion-Molecule Reactions......Page 28
Inelastic Processes......Page 29
Rearrangement Processes......Page 38
Charge Transfer Processes......Page 41
Literature Cited......Page 53
3 Laser Techniques for Determining State-to-State Reaction Rates*......Page 56
4 Studies of Multiphoton Dissociation of Polyatomic Molecules with Crossed Laser and Molecular Beams......Page 78
Experimental Arrangement......Page 79
Experimental Results and Discussion......Page 80
Concluding Remarks......Page 86
Literature Cited......Page 87
5 Molecular Beam Chemistry: Reaction Dynamics and Substituent Effects on the Electronic State of Carbonium Ions Produced in Ion-Molecule Reactions......Page 89
Literature Cited......Page 91
6 Reaction Product Identification from O(3P) + Benzene, Toluene, and 1,3,5-Trimethylbenzene Collisions......Page 93
Literature Cited......Page 99
7 Threshold Behavior for Collision-Induced Dissociation*......Page 100
Literature Cited......Page 104
8 Fourier Transform Doppler Spectroscopy: A New Tool for State-to-State Chemistry......Page 106
Literature Cited......Page 108
9 Total Cross Section Measurements of the Reaction Κ + HCl → KCl + H as a Function of Translational Energy......Page 109
Literature Cited......Page 112
10 Inter- and Intramolecular Energy Transfer Deduced from Macroscopic Infrared Laser Chemistry......Page 113
Relevant Properties of CHClF2.......Page 114
Photophysics of CHClF2 at 1088 cm-1.......Page 115
Photochemistry.......Page 116
Effect of Molecular Collisions During Laser Pulse.......Page 118
Discussion.......Page 121
Literature Cited......Page 122
11 Temperature Dependence of the Reaction of Nitric Oxide and Vibrationally Excited Ozone......Page 123
Literature Cited......Page 125
12 CO Product Vibrational Energy Distribution in the O(3P) + C3O2 Reaction......Page 127
Literature Cited......Page 129
F + RH......Page 130
Literature Cited......Page 132
14 Dynamics of the Electronically Chemiluminescent Reactions of O2(1Δ) with Olefins......Page 133
LITERATURE CITED......Page 135
15 Laser Induced Reaction Rate and Optical Absorption at Various Frequencies in the Absorption Bands of CF2ClCF2Cl and of CH3CF2Cl......Page 136
Literature Cited......Page 140
16 Chemiluminescence from the Gas Phase Reaction of Atomic Boron with the Alkali Metal Fluorides......Page 142
Literature Cited......Page 144
Experimental......Page 145
Results......Page 146
Literature Cited......Page 147
18 Laser Fluorescence and Thermal Lensing Studies of Intermode Energy Transfer and Chemical Reactivity in Small Polyatomic Molecules......Page 148
Experimental Methods......Page 149
Intermode Energy Transfer in SO2......Page 150
Intermode Energy Transfer in CH3F......Page 152
Energy Transfer in CH3F/SO2 Mixtures......Page 153
Collisional Propensity Rules for Vibrational Energy Transfer......Page 154
Metastable Vibrational Energy Distributions......Page 156
Laser Driven Chemical Reactions......Page 161
Literature Cited......Page 162
19 Molecular Dynamics of Electronic Energy Transfer: Quenching of Na(32P3/2) Atoms by NO Molecules......Page 164
Literature Cited......Page 168
20 Energy Transfer and Reaction in LiH Α1Σ......Page 170
Literature Cited......Page 173
21 Vibronic Excitation in Atom-Diatom Systems: N2+-He Collisions......Page 174
Literature Cited......Page 177
22 Mode-to-Mode Collisional Flow of Vibrational Energy within the S1 State of Benzene Vapor......Page 178
Literature Cited......Page 181
23 State-to-State Relaxation in Α2Σ+ OH and OD......Page 182
Literature Cited:......Page 184
24 Quantum Mechanics of Neutral Atom-Diatomic Molecule Reactions......Page 185
I. Reactive Scattering Theory......Page 186
II . The Three-Dimensional H + H2 Reaction......Page 189
III. The Collinear F + H2 Reaction......Page 193
IV. The Three-Dimensional F + H2 Reaction......Page 201
Literature Cited......Page 203
25 Collisions Involving Electronic Transitions......Page 206
Impact Parameter Treatments......Page 207
Multi-Dimensional Treatments......Page 210
Surface-Hopping......Page 213
Miller-George Theory......Page 218
Near-Resonance Effects......Page 221
Summary......Page 224
Literature Cited......Page 225
Surprisal Analysis......Page 226
Surprisal Synthesis......Page 232
The Road Ahead......Page 233
Literature Cited......Page 234
27 State-to-State Considerations in Reactions in Interstellar Clouds......Page 236
Literature Cited......Page 238
28 A New Helicity Representation for Reactive Atom-Diatom Collisions......Page 239
Literature Cited......Page 242
Translation to Vibration Energy Transfer from Different Initial States......Page 243
Literature Cited......Page 246
II. State Definition Near Dissociation.......Page 247
III. Thermal Energy Inelastic Collisions.......Page 248
V. Literature Cited.......Page 249
31 Molecular Vibration States: CH2 Asymmetric Stretch......Page 250
Literature Cited......Page 253
32 Thermochemical Properties for Atoms and Molecules in Specific Quantum States......Page 254
Literature Cited......Page 256
G......Page 257
R......Page 258
V......Page 259